Production of Bioethanol

Ethanol can be produced from biomass by the hydrolysis and sugar fermentation processes. Biomass wastes contain a complex mixture of carbohydrate polymers from the plant cell walls known as cellulose, hemi cellulose and lignin. In order to produce sugars from the biomass, the biomass is pre-treated with acids or enzymes in order to reduce the size of the feedstock and to open up the plant structure. The cellulose and the hemi cellulose portions are broken down (hydrolysed) by enzymes or dilute acids into sucrose sugar that is then fermented into ethanol. The lignin which is also present in the biomass is normally used as a fuel for the ethanol production plants boilers. There are three principle methods of extracting sugars from biomass

• Concentrated Acid Hydrolysis Process
  The Arkanol process works by adding 70-77% sulphuric acid to the biomass that has been dried to a 10% moisture content. The acid is added in the ratio of 1.25 acid to 1 biomass and the temperature is controlled to 50C. Water is then added to dilute the acid to 20-30% and the mixture is again heated to 100C for 1 hour. The gel produced from this mixture is then pressed to release an acid sugar mixture and a chromatographic column is used to separate the acid and sugar mixture.

• Dilute Acid Hydrolysis
  The dilute acid hydrolysis process is one of the oldest, simplest and most efficient methods of producing ethanol from biomass. Dilute acid is used to hydrolyse the biomass to sucrose. The first stage uses 0.7% sulphuric acid at 190C to hydrolyse the hemi cellulose present in the biomass. The second stage is optimised to yield the more resistant cellulose fraction. This is achieved by using 0.4% sulphuric acid at 215C.The liquid hydrolates are then neutralised and recovered from the process.

• Enzymatic Hydrolysis
  Instead of using acid to hydrolyse the biomass into sucrose, we can use enzymes to break down the biomass in a similar way. However this process is very expensive and is still in its early stages of development.
• Sugar Fermentation Process
  The hydrolysis process breaks down the cellulostic part of the biomass or corn into sugar solutions that can then be fermented into ethanol. Yeast is added to the solution, which is then heated. The yeast contains an enzyme called invertase, which acts as a catalyst and helps to convert the sucrose sugars into glucose and fructose (both C6H12O6)

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• Fractional Distillation Process
  The ethanol, which is produced from the fermentation process, still contains a significant quantity of water, which must be removed. This is achieved by using the fractional distillation process. The distillation process works by boiling the water and ethanol mixture. Since ethanol has a lower boiling point (78.3C) compared to that of water (100C), the ethanol turns into the vapour state before the water and can be condensed and separated.

Introduction to Bioethanol

Bio-ethanol is a first generation bio-fuel. Bio-ethanol is mainly produced by the sugar fermentation process, although it can also be manufactured by the chemical process of reacting ethylene with steam.

The main sources of sugar required to produce ethanol come from fuel or energy crops. These crops are grown specifically for energy use and include

• corn
• maize
• wheat crops
• waste straw
• willow and popular trees
• sawdust
• reed canary grass
  
• cord grasses

There is also ongoing research and development into the use of municipal solid wastes to produce ethanol fuel.

Ethanol can be used in petrol engines as a replacement for gasoline; it can be mixed with gasoline to any percentage. Most existing car petrol engines can run on blends of up to 15% bioethanol with petroleum/gasoline.